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Alternating CO 2 and bicycloalkane copolymerization to circular polyesters

Nature Sustainable Materials Min Zhu, Xavier Westworth, Yingluo Zhao, Gaurav S. Deshmukh, Deepak K. Barange, Tao Zhang, Ravikumar R. Gowda, Linda J. Broadbelt, Eugene Y.-X. Chen 2026-07-29

TL;DR - A simple organic catalyst directly copolymerizes COâ‚‚ with bicycloalkanes into high-performance polyesters. Selective depolymerization enables closed-loop recycling, potentially reducing both fossil feedstock use and plastic waste.

  • Produces alternating polyesters directly from COâ‚‚ and bicycloalkanes.
  • Uses a simple organic catalyst.
  • Supports selective depolymerization and material recovery.
  • Combines high-performance properties with a circular lifecycle.

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