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Octahedral-coordinated Co 3 O 4 for water electrolysis in acid

Nature Electrocatalysis Yue Wang, Yujin Ji, Jing Zhou, Jinxin Chen, Chenchen Li, Chendi Zhao, Jia Ke, Yutian Xiong, Sihui Pan, Wei-Hsiang Huang, Chih-Wen Pao, Chang-Yang Kuo, Chien-Te Chen, Youyong Li, Zhiwei Hu, Qi Shao, Xiaoqing Huang 2026-07-29

TL;DR - Researchers developed a trigonal Co₃O₄ electrocatalyst with edge-shared octahedral coordination that improves acidic oxygen evolution performance. It combines lower overpotential with reduced cobalt dissolution compared with spinel Co₃O₄.

  • Produced via a vacuum-mediated molten-alkali mechanochemical method.
  • Features a new trigonal phase rather than the conventional spinel structure.
  • Achieves lower overpotential during acidic oxygen evolution.
  • Reduces cobalt dissolution, indicating improved catalyst stability.

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