A radical approach to making C-glycoside molecules
Merged summary
TL;DR - Researchers developed a platform for synthesizing C-glycosides from sugars using glycosyl sulfonyl hydrazides as accessible free-radical precursors. It enables targeted, stereospecific carbon–carbon bond formation across carbohydrate scaffolds.
- Uses readily accessible glycosyl sulfonyl hydrazides to generate free radicals.
- Forms robust carbon–carbon linkages in C-glycoside molecules.
- Controls the desired 3D arrangement of atoms during synthesis.
- Offers a general strategy for constructing valuable carbohydrate-derived compounds.
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A radical approach to making C-glycoside molecules
TL;DR - Researchers developed a platform for synthesizing C-glycosides from sugars using glycosyl sulfonyl hydrazides as accessible free-radical precursors. It enables targeted, stereospecific carbon–carbon bond formation across carbohydrate scaffolds.
- Uses readily accessible glycosyl sulfonyl hydrazides to generate free radicals.
- Forms robust carbon–carbon linkages in C-glycoside molecules.
- Controls the desired 3D arrangement of atoms during synthesis.
- Offers a general strategy for constructing valuable carbohydrate-derived compounds.